From aiba-: at :-volta.vmsmail.ethz.ch Thu Aug 4 07:29:32 1994 Received: from bernina.ethz.ch for aiba "-at-" volta.vmsmail.ethz.ch by www.ccl.net (8.6.9/930601.1506) id GAA07432; Thu, 4 Aug 1994 06:44:52 -0400 Message-Id: <199408041044.GAA07432 _-at-_)www.ccl.net> Received: from VOLTA.vmsmail.ethz.ch by bernina.ethz.ch id <06550-0 ":at:" bernina.ethz.ch>; Thu, 4 Aug 1994 12:50:04 +0200 X-Vms-To: ethz::"chemistry _-at-_)ccl.net" To: chemistry;at;ccl.net From: aiba: at :volta.vmsmail.ethz.ch (Aiaz Bakassov, Phys. Chem., ETH Zurich) Subject: Reply to T. Daniel Crawford Date: Thu, 4 Aug 1994 12:50:04 +0200 Dear Daniel Crawford, > I have also derived this expression, > but obtained the same answer as S&O. Yes, their expression is the correct one. Who said it is incorrect ? What I was posting was absolutely about my own failure, and all wanted was to make sure that the expression in the book is correct and free from misprints for example. > I believe that if you derive the equation > using second-quantization that > you will obtain the correct result. That's exactly what I have done and got exactly their result. I have already responded to some people that I had got the S&O result using second quantization. The latter is a tool I am really used to, for I am a pure theoretical physicist and am in the quantum chemistry business for a year may be for two -- what an accident of life! :-) My problem was that I was failing to get their result, using that clumsy determinantal technique. Which merely means that I am still missing some point in the book. It is a purely working situation and those who wished to help me (without any other prejudice intended) directed their mails to me. Science must be free from destructive emotions. Sincerely, Ayaz Bakasov.