CCL:G: optimizations in gaussian break symmetry



 Sent to CCL by: zborowsk_-_chemia.uj.edu.pl
 Dear Ben
 Are you sure it is symmetry breaking
 It will be very strange
 Probably Gaussian did not break symmetry of your system but opposite
 process occured
 For me you should take the last coordinates and restart calculations with
 the new symmetry group
 If you want to avoid this next time (and if you do not want to be informed
 that your system changed symmetry) you should probably use the "NoSymm
 "command
 > Sent to CCL by: "Ben Vastine" [vastinator===gmail.com]
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 > does anyone know how to avoid breaking the symmetry in optimizations in
 > Gaussian?  for example, here is the end of one my files:
 >
 > Leave Link  103 at Fri Oct 13 02:55:01 2006, MaxMem=   73400320 cpu:
 > 10.1
 >  (Enter /home/chem1/g03_dir/g03/l202.exe)
 >  Stoichiometry    C34H53P2Rh
 >  Framework group  C2[C2(RhH),X(C34H52P2)]
 >  Deg. of freedom   132
 >  Full point group                 C2      NOp   2
 >  Omega: Change in point group or standard orientation.
 >
 >  Old FWG=C02  [C2(H1Rh1),X(C34H52P2)]
 >  New FWG=C02  [C2(Rh1H1),X(C34H52P2)]
 >  Error termination via Lnk1e in /home/chem1/g03_dir/g03/l202.exe at Fri
 > Oct
 > 13 02:55:03 2006.
 >
 > I've tried to change the grid, but I've had no success with that idea.
 > What
 > about step size?
 >
 > Thanks.
 >
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 > does anyone know how to avoid breaking the symmetry in optimizations in
 > Gaussian?  for example, here is the end of one my files:
 > <br><br>Leave Link&nbsp; 103 at Fri Oct 13 02:55:01 2006,
 > MaxMem=&nbsp;&nbsp; 73400320
 cpu:&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;
 > 10.1<br>&nbsp;(Enter /home/chem1/g03_dir/g03/l202.exe)
 > <br>&nbsp;Stoichiometry&nbsp;&nbsp;&nbsp;
 C34H53P2Rh<br>&nbsp;Framework
 > group&nbsp; C2[C2(RhH),X(C34H52P2)]<br>&nbsp;Deg. of
 freedom&nbsp;&nbsp;
 > 132<br>&nbsp;Full point
 >
 group&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;
 > C2&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;
 NOp&nbsp;&nbsp; 2<br>&nbsp;Omega: Change
 > in point group or standard orientation.<br><br>
 > &nbsp;Old FWG=C02&nbsp;
 [C2(H1Rh1),X(C34H52P2)]<br>&nbsp;New FWG=C02&nbsp;
 > [C2(Rh1H1),X(C34H52P2)]<br>&nbsp;Error termination via Lnk1e in
 > /home/chem1/g03_dir/g03/l202.exe at Fri Oct 13 02:55:03
 2006.<br><br>I've
 > tried to change the grid, but I've had no success with that idea.&nbsp;
 > What about step size?
 > <br><br>Thanks.<br><br>
 >
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 >
 >
 --
 Krzysztof Zborowski
 Faculty of Chemistry
 Jagiellonian University
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