From owner-chemistry@ccl.net Thu Jul 11 07:27:01 2019
From: "Benoit Gearald ablux13-x-gmail.com" <owner-chemistry:-:server.ccl.net>
To: CCL
Subject: CCL: Barrierless channel
Message-Id: <-53791-190711072150-11746-wsnC1oRmKSkmT5b0vLTfnQ:-:server.ccl.net>
X-Original-From: "Benoit  Gearald" <ablux13^gmail.com>
Date: Thu, 11 Jul 2019 07:21:48 -0400


Sent to CCL by: "Benoit  Gearald" [ablux13(a)gmail.com]
Dear CCLers,

I'm studying a multichannel reaction. I've found a barrierless channel i.e. 
the transition state is below the intermediate and I have confirmed that by 
different methods of calculation.  
My question is whether I have to locate a molecular complex that links the 
intermediate to the TS or it's ok as it is?

I'm really confused on that point and need some explanations and 
clarifications.

Best regards,

Benoit