From owner-chemistry@ccl.net Sun Feb  5 13:03:01 2006
From: "Jim Kress ccl_nospam*|*kressworks.com" <owner-chemistry%server.ccl.net>
To: CCL
Subject: CCL: Aquous electrochemistry
Message-Id: <-30785-060205125416-4413-ElOnE5D8K/L9qiC+bqEByw%server.ccl.net>
X-Original-From: "Jim Kress" <ccl_nospam%%kressworks.com>
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Date: Sun, 5 Feb 2006 12:54:13 -0500
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Sent to CCL by: "Jim Kress" [ccl_nospam[a]kressworks.com]
Would you please post a summary of the answers you receive?

Thanks.

Jim 

> -----Original Message-----
> From: nokophala.,.aim.com [mailto:owner-chemistry,ccl.net] 
> Sent: Sunday, February 05, 2006 10:22 AM
> To: Kress, Jim 
> Subject: CCL: Aquous electrochemistry
> 
> Sent to CCL by: nokophala++aim.com
> 
> Hi There,
> Is anyone aware of successes in reproducing some of the 
> tabulated redox potentials of electrochemical reactions that 
> ar elisted i standard electrochemical tables, especiall those 
> involving single ions? e.g. Cu 
> --> Cu2+(aq) + 2e-. The key issue that I need coment on here is the
> selection of appropriate solvation models. I doubt if 
> continuum models would require inclusion of at least the 
> first shell of water molecules, as these are strongly bound. 
> As a starting point I am trying to reproduce the experimental 
> value of the 'reference' reaction 2H+ +2e = H2. Even this 
> appears tricky.
> 
> Thanks in advance,
> 
> Noko Phala, Anglo Research
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