CCL: Aquous electrochemistry

 Sent to CCL by: nokophala!A!aim.com
 I will do that.
 Noko
 -----Original Message-----
 
 From: Jim Kress ccl_nospam*|*kressworks.com <owner-chemistry,ccl.net>
 
 To: Phala, Noko  <nokophala,aim.com>
 Sent: Sun, 5 Feb 2006 13:08:33 -0500
 Subject: CCL: Aquous electrochemistry
  Sent to CCL by: "Jim Kress" [ccl_nospam[a]kressworks.com]
 Would you please post a summary of the answers you receive?
 Thanks.
 Jim
 
 -----Original Message-----
 From: nokophala. : .aim.com [mailto:owner-chemistry : ccl.net]
 Sent: Sunday, February 05, 2006 10:22 AM
 To: Kress, Jim
 Subject: CCL: Aquous electrochemistry
 Sent to CCL by: nokophala++aim.com
 Hi There,
 Is anyone aware of successes in reproducing some of the
 tabulated redox potentials of electrochemical reactions that
 ar elisted i standard electrochemical tables, especiall those
 involving single ions? e.g. Cu
 --> Cu2+(aq) + 2e-. The key issue that I need coment on here is the
 selection of appropriate solvation models. I doubt if
 continuum models would require inclusion of at least the
 first shell of water molecules, as these are strongly bound.
 As a starting point I am trying to reproduce the experimental
 value of the 'reference' reaction 2H+ +2e = H2. Even this
 appears tricky.
 Thanks in advance,
 Noko Phala, Anglo Research
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