CCL: Opt Ir



 Sent to CCL by: [eurisco1=pochta.ru]
 Dear Enrico,
 
Once more suggestions related to your input fule and input kindly provided by Mr. Quartarolo Domenico:
 
1) you don't need geom=connectivity if you use quantum chemical methods. Moreover this keyword is excess if you don't provide the connectivity information. 2) I would suggest to use %mem and %nproc keywords to manage with RAM and number of cores which are available to the job execution. It will be more effective way to achieve results.
 I hope that it will be helpful.
 Sincerely,
 Ol Ga
 PS: Happy New Year and Happy Computing!
 
-----ÐÑÑÐÐÐÐÐ ÑÐÐÐÑÐÐÐÐ-----
 From: quartarolo.:.unical.it
 
 Sent: Monday, January 02, 2012 12:20 AM
 
To: Ga, Ol Subject: CCL: Opt Ir
 Sent to CCL by: quartarolo()unical.it
 Hi Enrico,
 the basis set you specified for H, C, N is actually the 6-311G** (not
 the 6-31G**)
 Try this more simplified input, it should run correctly:
 %chk=C:\Users\Enrico D\Desktop\untitled.chk
 # opt b3lyp/gen geom=connectivity pop=readradii pseudo=read
 Title Card Required
 0 2
   C                  4.52524339   -0.09789019    2.09918254
   C                  3.58526629   -0.89810430    2.66166782
   C                  2.16060863   -0.87790671    2.08644558
   N                  1.89131084   -0.10912498    1.06781310
   C                  2.87063215    0.79462362    0.50077553
   C                  4.14433529    0.82203192    0.93328089
   C                  2.36495899   -1.07611783   -1.73532275
   C                  3.07282971   -2.04729069   -2.35808347
   C                  2.67158031   -3.52286997   -2.16711577
   C                  1.63540872   -3.82039466   -1.35136189
   C                  0.92544191   -2.66284087   -0.61696888
   N                  1.25038260   -1.42865530   -0.84065937
   C                  2.27458504    1.68822117   -0.59281571
   C                 -0.17709921   -2.84028339    0.44788877
   N                  1.02790642    1.46791074   -0.85299512
   C                  0.27047404    2.31633228   -1.78632456
   C                  0.88180505    3.34262513   -2.42805988
   C                  2.39321155    3.57664864   -2.19460938
   C                  3.05829404    2.78634339   -1.33361539
   C                 -0.70639411   -4.02371643    0.81746027
   C                 -1.78308419   -4.02577927    1.91154722
   C                 -2.14598961   -2.83846944    2.46041817
   C                 -1.48703818   -1.52572133    1.96649518
   N                 -0.61883464   -1.57713716    1.02721368
   C                  0.00317921    2.59457560    1.23445649
   C                 -2.00068776   -1.75537921   -1.15250447
   C                 -3.30959452   -2.04007365   -1.42630746
   C                 -4.39639936   -0.99840846   -1.14450162
   C                 -4.01934124    0.21259440   -0.68009321
   C                 -2.53701277    0.45101721   -0.34391680
   N                 -1.64496872   -0.46292074   -0.54224945
   C                 -2.00436700    1.75465046    0.25497495
   N                 -0.63235221    1.64078279    0.63043748
   C                 -2.70806131    2.89722014    0.42202369
   C                 -1.98581367    4.09670511    1.03068660
   C                 -0.69970689    3.95276783    1.43536085
   Ir                 0.20196186   -0.05942432    0.09007759
   C                 -2.69947791    5.44015676    1.17583915
   C                 -5.88263065   -1.31768418   -1.36582379
   H                  5.52477236   -0.10493351    2.46044743
   H                  3.82649437   -1.53664648    3.48829239
   H                  1.39634830   -1.49388882    2.50469339
   H                  4.86806643    1.45044888    0.47625965
   H                  2.62364433   -0.04867091   -1.88561675
   H                  3.89418142   -1.79329586   -2.99220542
   H                  3.19397990   -4.30229742   -2.68511152
   H                  1.31721395   -4.83716921   -1.22805178
   H                 -0.75919384    2.12854818   -1.96194227
   H                  0.32981645    3.98394670   -3.08566184
   H                  2.89570579    4.35974192   -2.70595458
   H                  4.11516211    2.92237061   -1.16173806
   H                 -0.37737595   -4.93096285    0.36873421
   H                 -2.24265851   -4.93827433    2.22891500
   H                 -2.87415955   -2.81220394    3.23922825
   H                 -1.73922652   -0.58965493    2.38944166
   H                  0.99228408    2.44563809    1.55899263
   H                 -1.24456564   -2.47342388   -1.35666764
   H                 -3.57950279   -2.99553077   -1.82065418
   H                 -4.73714534    0.98963747   -0.54389424
   H                 -3.73623277    2.96959671    0.13831815
   H                 -0.17656624    4.76521447    1.88674474
   H                 -2.29104719    5.95573156    2.01578638
   H                 -2.56726005    6.03898443    0.29550235
   H                 -3.73804492    5.25603739    1.33016926
   H                 -6.40412091   -0.42280596   -1.63561403
   H                 -5.98729174   -2.03846204   -2.15247805
   H                 -6.28981462   -1.71557160   -0.46128773
 H C N 0
 6-311G**
 ****
 Ir 0
 LANL2DZ
 ****
 Ir 0
 LANL2DZ
 Ir 0.82
 best regards
 Quartarolo Domenico
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