CCL: Query on radiative decay rate constant formula
- From: "Sergio Manzetti" <sergio.manzetti ..
gmx.com>
- Subject: CCL: Query on radiative decay rate constant formula
- Date: Fri, 25 Jan 2013 11:18:59 +0100
Hi Elizabeth,
It seems their relationship is (2.5x10^5 x c^3) / pi x epsilon
This formulation is unknown, at least to me, but it seems this implies a
different radial decay, perhaps related to a perturbated condition of some sort.
Sergio
----- Original Message -----
> From: Eli Lam elizabeth.shlam||gmail.com
Sent: 01/25/13 09:38 AM
To: Manzetti, Sergio
Subject: CCL: Query on radiative decay rate constant formula
Sent to CCL by: "Eli Lam" [elizabeth.shlam _ gmail.com] Dear CCLers,
I have been reading papers on radiative decay rate constant. In general, people
start of with the formulae: ((16x10^6 pi^3 E^3) /3h(epsilon))* (transition
dipole moments), where h is the Planck's constant, epsilon is the vacuum
permittivity, and E is the excitation energy, (Inorganic Chemistry, 42, 20,
2003). Yersin starts with the formulae: (64pi^4 E^3 / 3hc^3) *(transition dipole
moments), where c is the speed of light (Coordination Chemistry Reviews 255,
2622, 2011). I would like to ask 1) How is the two formula related? 2) How is
these two formula derived? Thank you very much! Elihttp://www.ccl.net/cgi-bin/ccl/send_ccl_messagehttp-:-//www.ccl.net/chemistry/sub_unsub.shtmlhttp-:-//www.ccl.net/spammers.txt--========GMXBoundary220991359109139981905
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<span style=3D'font-family:Verdana'><span
style=3D'font-size:12px'>Hi Eliza=
beth,<br />=20
<br />=20
It seems their relationship is (2.5x10^5 x c^3) / pi x epsilon<br />=20
<br />=20
<br />=20
This formulation is unknown, at least to me, but it seems this implies a di=
fferent radial decay, perhaps related to a perturbated condition of some so=
rt.<br />=20
<br />=20
Sergio<br />=20
<br />=20
<p style=3D"margin:0px; padding:0px;" >=20
=C2=A0</p>=20
<blockquote style=3D"border-left: 1px solid #CCC; padding-left: 5px;
margin=
-left: 5px; margin-bottom: 0px; margin-top: 0px; margin-right: 0px;" type=
=3D"cite">=20
<p style=3D"margin:0px; padding:0px;" >=20
<span style=3D"font-family:Verdana"><span
style=3D"font-size:12px">----- =
Original Message -----</span></span></p>=20
<p style=3D"margin:0px; padding:0px;" >=20
<span style=3D"font-family:Verdana"><span
style=3D"font-size:12px">From: =
Eli Lam elizabeth.shlam||gmail.com</span></span></p>=20
<p style=3D"margin:0px; padding:0px;" >=20
<span style=3D"font-family:Verdana"><span
style=3D"font-size:12px">Sent: =
01/25/13 09:38 AM</span></span></p>=20
<p style=3D"margin:0px; padding:0px;" >=20
<span style=3D"font-family:Verdana"><span
style=3D"font-size:12px">To: Ma=
nzetti, Sergio </span></span></p>=20
<p style=3D"margin:0px; padding:0px;" >=20
<span style=3D"font-family:Verdana"><span
style=3D"font-size:12px">Subjec=
t: CCL: Query on radiative decay rate constant
formula</span></span></p>=20
<br />=20
<div>=20
<div>=20
<pre style=3D"white-space: pre-wrap; word-wrap: break-word;
font-size:11=
;pre">=20
Sent to CCL by: "Eli Lam" [elizabeth.shlam _ gmail.com]=20
Dear CCLers,=20
I have been reading papers on radiative decay rate constant. In general,=
=20
people start of with the formulae: ((16x10^6 pi^3 E^3) /3h(epsilon))*=20
(transition dipole moments), where h is the Planck's constant, epsilon is t=
he=20
vacuum permittivity, and E is the excitation energy, (Inorganic Chemistry, =
42,=20
20, 2003). Yersin starts with the formulae: (64pi^4 E^3 / 3hc^3) *(transit=
ion=20
dipole moments), where c is the speed of light (Coordination Chemistry Revi=
ews=20
255, 2622, 2011). =20
I would like to ask=20
1) How is the two formula related?=20
2) How is these two formula derived?=20
Thank you very much!=20
Eli=20
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Subscribe/Unsubscribe:=20=20=20
Job: http://www.ccl.net/jobs=20=20=20=20=20</pre>=20
</div>=20
</div>=20
</blockquote>=20
<p style=3D"margin:0px; padding:0px;" >=20
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<br />=20
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