CCL: Query on radiative decay rate constant formula



Hi Elizabeth,
  It seems their relationship is (2.5x10^5 x c^3) / pi x epsilon
  This formulation is unknown, at least to me, but it seems this implies a
 different radial decay, perhaps related to a perturbated condition of some sort.
  Sergio
 ----- Original Message -----
 > From: Eli Lam elizabeth.shlam||gmail.com
 Sent: 01/25/13 09:38 AM
 To: Manzetti, Sergio
 Subject: CCL: Query on radiative decay rate constant formula
  Sent to CCL by: "Eli Lam" [elizabeth.shlam _ gmail.com] Dear CCLers,
 I have been reading papers on radiative decay rate constant. In general, people
 start of with the formulae: ((16x10^6 pi^3 E^3) /3h(epsilon))* (transition
 dipole moments), where h is the Planck's constant, epsilon is the vacuum
 permittivity, and E is the excitation energy, (Inorganic Chemistry, 42, 20,
 2003). Yersin starts with the formulae: (64pi^4 E^3 / 3hc^3) *(transition dipole
 moments), where c is the speed of light (Coordination Chemistry Reviews 255,
 2622, 2011). I would like to ask 1) How is the two formula related? 2) How is
 these two formula derived? Thank you very much! Elihttp://www.ccl.net/cgi-bin/ccl/send_ccl_messagehttp-:-//www.ccl.net/chemistry/sub_unsub.shtmlhttp-:-//www.ccl.net/spammers.txt--========GMXBoundary220991359109139981905
 Content-Type: text/html; charset="utf-8"
 Content-Transfer-Encoding: quoted-printable
 <span style=3D'font-family:Verdana'><span
 style=3D'font-size:12px'>Hi Eliza=
 beth,<br />=20
 <br />=20
 It seems their relationship is (2.5x10^5 x c^3) / pi x epsilon<br />=20
 <br />=20
 <br />=20
 This formulation is unknown, at least to me, but it seems this implies a di=
 fferent radial decay, perhaps related to a perturbated condition of some so=
 rt.<br />=20
 <br />=20
 Sergio<br />=20
 <br />=20
 <p style=3D"margin:0px; padding:0px;" >=20
 	=C2=A0</p>=20
 <blockquote style=3D"border-left: 1px solid #CCC; padding-left: 5px;
 margin=
 -left: 5px; margin-bottom: 0px; margin-top: 0px; margin-right: 0px;" type=
 =3D"cite">=20
 	<p style=3D"margin:0px; padding:0px;" >=20
 		<span style=3D"font-family:Verdana"><span
 style=3D"font-size:12px">----- =
 Original Message -----</span></span></p>=20
 	<p style=3D"margin:0px; padding:0px;" >=20
 		<span style=3D"font-family:Verdana"><span
 style=3D"font-size:12px">From: =
 Eli Lam elizabeth.shlam||gmail.com</span></span></p>=20
 	<p style=3D"margin:0px; padding:0px;" >=20
 		<span style=3D"font-family:Verdana"><span
 style=3D"font-size:12px">Sent: =
 01/25/13 09:38 AM</span></span></p>=20
 	<p style=3D"margin:0px; padding:0px;" >=20
 		<span style=3D"font-family:Verdana"><span
 style=3D"font-size:12px">To: Ma=
 nzetti, Sergio </span></span></p>=20
 	<p style=3D"margin:0px; padding:0px;" >=20
 		<span style=3D"font-family:Verdana"><span
 style=3D"font-size:12px">Subjec=
 t: CCL: Query on radiative decay rate constant
 formula</span></span></p>=20
 	<br />=20
 	<div>=20
 		<div>=20
 			<pre style=3D"white-space: pre-wrap; word-wrap: break-word;
 font-size:11=
 ;pre">=20
 Sent to CCL by: "Eli  Lam" [elizabeth.shlam _ gmail.com]=20
 Dear CCLers,=20
 I have been reading papers on radiative decay rate constant.  In general,=
 =20
 people start of with the formulae: ((16x10^6 pi^3 E^3) /3h(epsilon))*=20
 (transition dipole moments), where h is the Planck's constant, epsilon is t=
 he=20
 vacuum permittivity, and E is the excitation energy, (Inorganic Chemistry, =
 42,=20
 20, 2003).  Yersin starts with the formulae: (64pi^4 E^3 / 3hc^3) *(transit=
 ion=20
 dipole moments), where c is the speed of light (Coordination Chemistry Revi=
 ews=20
 255, 2622, 2011). =20
 I would like to ask=20
 1) How is the two formula related?=20
 2) How is these two formula derived?=20
 Thank you very much!=20
 Eli=20
 -=3D This is automatically added to each message by the mailing script =3D-=
 =20=20=20=20=20=20=20=20
 Subscribe/Unsubscribe:=20=20=20
 Job: http://www.ccl.net/jobs=20=20=20=20=20</pre>=20
 		</div>=20
 	</div>=20
 </blockquote>=20
 <p style=3D"margin:0px; padding:0px;" >=20
 	=C2=A0</p>=20
 <br />=20
 </span></span>