CCL: HOMO energy and redox potential

[Muhammad Abduh Nasution <abduh/./mhs.unimed.ac.id>]

 Hi Adam,
Thanks very much for your answer. Previously I've plot it with
 r^500
on MS Excel and I find for higher order exponent it's R squared
 is
higher.
Let me explain the background. From collision theory equation,
 I think
it is similiar to volumetric flow rate equation. So I try to
 derive
volumetric flow rate equation to obtain reaction rate equation.
 I
found equation k = ('ain x Ek)/(Mr x r^5)
where k= reaction rate
 constant, 'ain = coefficient, Ek = kinetic
energy, Mr = relative mass, r
 = radius. So I plot k from this equation
with ionization potential as HOMO
 energy.
On the other hands, I think Arrhenius equation and Eyring equation
 has
similiarity to this problem, because reaction rate constant
 is
exponential of energy form.
Correct me if I'm
 wrong.
Best,


Muhammad Abduh