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QCMP141. A PC-Based General Program for the Simulation and
Analysis of Cyclic Voltammetric Experiments
by David K. Gosser, Jr., and Feng Zhang, Department of Chemistry, The City College of the City University of New York, New York 10031 GPS-CV utilizes advances in simulation methodology that increase efficiency, allow for generality of mechanism, and include IR drop and capacitive current effects. An accessible user interface is used, and a graphical analysis program is provided. Cyclic voltammograms for nearly any mechnism can be simulated by the user. A companion program, CVFIT, combines the GPS-CV program with a least-squares fit by SIMPLEX minimization to give the best-fit parameters, with error estimates. The use of CVFIT is demonstrated with a three-parameter fit of experimental cyclic voltammograms. Lines of Code: 3388 PASCAL |