CCL Home Page
Up Directory CCL polar.txt
  Polar 3.2 for Windows: Electrochemical simulation and data analysis

		W.S. Ping Company
124 Eastern Avenue, Kingsford, Sydney, NSW 2032, Australia			
Phone: 61 2 96620516, 0413 008 019	
mailto:polarography@bigfoot.com, showing@bigfoot.com
http://www.bigfoot.com/~polarography/
http://www.bigfoot.com/~showing/ 			

	It analytically and digitally simulates voltammograms (polarograms) 
on about 20 mechanisms at 8 electrode geometries (planar, spherical, semi-
spherical, cylindrical, semi-cylindrical, microdisc, thin film, and rotating 
electrodes) in over 5 techniques (linear sweep and CV, DC, normal pulse, 
differential pulse, and square wave voltammetries), and outputs current, 
resitance, conductivity and surface concentration. It also simulates effects 
of charge current, resistance, noise, electrolyte, stripping time, stripping 
potential, etc.

	It analyses any x-y data for detecting peak location, peak value, 
semi-derivative, derivative, intergral, semi-intergral, curve fitting, 
and separating overlapped peaks.

	It shows a tip when the user put mouse cursor over a lable. It can 
separate overlapped voltammograms into individuals, and extract real peaks 
from voltammogram with noise and baseline. Users can compare by the 
theoretical peak values, analytically and digitally simulation, and choose 
to extract which kinetic pararmeters. Its data can be imported into other 
program (e.g. MS Excel).

	It has been successfully applied to fit experimental 
polarograms (voltammograms) of In(III), Cd(II), Pb(II), Tl(I), Cr(III).
Zn(II), and binuclear copper complex in aqueous and non-aqueous media 
at mercury, solid metal and non-metal electrodes (specifically the 
dropping mercury, hanging mercury drop, gold, platinum and glassy 
carbon electrodes) by various electrochemical techniques (differential 
pulse, sqware wave, and pseudo-derivative normal pulse polargraphies) [1].

	Its 32-bit version Polar32 runs on IBM PC under Windows 3.11/95/98/NT 
while its 16-bit version Polar32b runs under Windows 3/3.1/3.11/95/98/NT. 
They are available from the author or download from my Web site.
	
	REFERENCES
[1] W. Huang, T. Henderson, A.M. Bond and K.B. Oldham, Curve fitting 
    to resolve overlapping voltammetric peaks: model and examples, 
    Anal. Chim. Acta, 1995, 304, 1-15.
Modified: Wed Feb 3 06:58:00 1999 GMT
Page accessed 1518 times since Tue Nov 17 01:12:34 2009 GMT